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The term 'free chlorine residual' specifically refers to the amount of uncombined chlorine that remains in the water after chlorine has been added for disinfection purposes. This residual is crucial for ensuring that the water remains safe by preventing the growth of harmful microorganisms. Free chlorine is still in its active form and effective in disinfecting, which is why monitoring its levels is essential for water treatment processes.

In contrast, chlorine that has combined with other substances, such as ammonia, forms what is known as combined chlorine, which does not contribute to disinfection in the same way. Chlorine that is no longer effective typically refers to combined chlorine, which doesn’t provide the same sanitizing benefits. Additionally, while chlorine may need to be replenished over time due to factors like usage, water demand, and degradation, the essence of 'free chlorine residual' itself is the amount of effective, uncombined chlorine available at any given time.